Angelina Jolie – Then

Angelina Jolie has long been considered one of the most attractive women in the world, and in 2005, her Mr. & Mrs. Smith co-star Brad Pitt seemed to notice. She was accused of being the reason Brad and Jennifer Aniston divorced, but either way, the two started a relationship at the end of 2005.

Their first daughter was born in May 2006. They also welcomed twins in July 2008. In addition to their three biological children, they had three adopted children. They were married in August 2014, but their divorce followed just two years later, in September 2016. She accused Brad of being physically aggressive and having substance issues.

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